A glass transition scenario based on heterogeneities and entropy barriers

We propose a scenario for the glass transition based on the cooperative nature of nucleation processes and entropic effects. The main point is the relation between the off-equilibrium energy dissipation and nucleation processes in off-equilibrium supercooled liquids which leads to a natural definition of the complexity. From the absence of coarsening growth we can derive an entropy based fluctuation formula which relates the free energy dissipation rate in the glass with the nucleation rate of the largest cooperative regions. As by-product we obtain a new phenomenological relation between the largest relaxation time in the supercooled liquid phase and an effective temperature. This differs from the Adam-Gibbs relation in that predicts no divergence of the primary relaxation time at the Kauzmann temperature and the existence of a crossover from fragile to strong behavior.Comment: 8th International Workshop on Disordered Systems, Andalo (Trento), Italy, 12-15 March 200

Inherent Structures, Configurational Entropy and Slow Glassy Dynamics

We give a short introduction to the inherent structure approach, with particular emphasis on the Stillinger and Weber decomposition, of glassy systems. We present some of the results obtained in the framework of spin-glass models and Lennard-Jones glasses. We discuss how to generalize the standard Stillinger and Weber approach by including the entropy of inherent structures. Finally we discuss why this approach is probably insufficient to describe the behavior of some kinetically constrained models.Comment: 16 pages, 8 figures, Contribution to the ESF SPHINX meeting `Glassy behaviour of kinetically constrained models' (Barcelona, March 22-25, 2001

Is the Stillinger and Weber decomposition relevant for coarsening models?

We study three kinetic models with constraint, namely the Symmetrically Constrained Ising Chain, the Asymmetrically Constrained Ising Chain, and the Backgammon Model. All these models show glassy behavior and coarsening. We apply to them the Stillinger and Weber decomposition, and find that they share the same configurational entropy, despite of their different nonequilibrium dynamics. We conclude therefore that the Stillinger and Weber decomposition is not relevant for this type of models.Comment: 14 pages, 12 figure

Frequency-domain study of relaxation in a spin glass model for the structural glass transition

We have computed the time-dependent susceptibility for the finite-size mean-field Random Orthogonal model (ROM). We find that for temperatures above the mode-coupling temperature the imaginary part of the susceptibility $\chi''(\nu)$ obeys the scaling forms proposed for glass-forming liquids. Furthermore, as the temperature is lowered the peak frequency of $\chi''$ decreases following a Vogel-Fulcher law with a critical temperature remarkably close to the known critical temperature $T_c$ where the configurational entropy vanishes.Comment: 7 pages, 4 figures, epl LaTeX packag

Barriers in the p-spin interacting spin-glass model. The dynamical approach

We investigate the barriers separating metastable states in the spherical p-spin glass model using the instanton method. We show that the problem of finding the barrier heights can be reduced to the causal two-real-replica dynamics. We find the probability for the system to escape one of the highest energy metastable states and the energy barrier corresponding to this process.Comment: 4 pages, 1 figur

Inherent structures and non-equilibrium dynamics of 1D constrained kinetic models: a comparison study

e discuss the relevance of the Stillinger and Weber approach to the glass transition investigating the non-equilibrium behavior of models with non-trivial dynamics, but with simple equilibrium properties. We consider a family of 1D constrained kinetic models, which interpolates between the asymmetric chain introduced by Eisinger and J\"ackle [Z. Phys. {\bf B84}, 115 (1991)] and the symmetric chain introduced by Fredrickson and Andersen [Phys. Rev. Lett {\bf 53}, 1244 (1984)], and the 1D version of the Backgammon model [Phys. Rev. Lett. {\bf 75}, 1190 (1995)]. We show that the configurational entropy obtained from the inherent structures is the same for all models irrespective of their different microscopic dynamics. We present a detailed study of the coarsening behavior of these models, including the relation between fluctuations and response. Our results suggest that any approach to the glass transition inspired by mean-field ideas and resting on the definition of a configurational entropy must rely on the absence of any growing characteristic coarsening pattern.Comment: 32 pages, 28 figures, RevTe

Activated processes and Inherent Structure dynamics of finite-size mean-field models for glasses

We investigate the inherent structure (IS) dynamics of mean-field {\it finite-size} spin-glass models whose high-temperature dynamics is described in the thermodynamic limit by the schematic Mode Coupling Theory for super-cooled liquids. Near the threshold energy the dynamics is ruled by activated processes which induce a logarithmic slow relaxation. We show the presence of aging in both the IS correlation and integrated response functions and check the validity of the one-step replica symmetry breaking scenario in the presence of activated processes. Our work shows: 1) The violation of the fluctuation-dissipation theorem is given by the configurational entropy, 2) The intermediate time regime ($\log(t)\sim N$) in mean-field theory automatically includes activated processes opening the way to analytically investigate activated processes by computing corrections beyond mean-field.Comment: 8 pages, 3 postscript figures, EPL format, improved versio

Slow and fast dynamics in coupled systems: A time series analysis view

We study the dynamics of systems with different time scales, when access only to the slow variables is allowed. We use the concept of Finite Size Lyapunov Exponent (FSLE) and consider both the case when the equations of motion for the slow components are known, and the situation when a scalar time series of one of the slow variables has been measured. A discussion on the effects of parameterizing the fast dynamics is given. We show that, although the computation of the largest Lyapunov exponent can be practically infeasible in complex dynamical systems, the computation of the FSLE allows to extract information on the characteristic time and on the predictability of the large-scale, slow-time dynamics even with moderate statistics and unresolved small scales.Comment: 17 pages RevTeX, 6 PostScript figures, tarred, gzipped, uuencoded. Submitted to Physica

Intermittency of glassy relaxation and the emergence of a non-equilibrium spontaneous measure in the aging regime

We consider heat exchange processes between non-equilibrium aging systems (in their activated regime) and the thermal bath in contact. We discuss a scenario where two different heat exchange processes concur in the overall heat dissipation: a stimulated fast process determined by the temperature of the bath and a spontaneous intermittent process determined by the fact that the system has been prepared in a non-equilibrium state. The latter is described by a probability distribution function (PDF) that has an exponential tail of width given by a parameter $\lambda$, and satisfies a fluctuation theorem (FT) governed by that parameter. The value of $\lambda$ is proportional to the so-called effective temperature, thereby providing a practical way to experimentally measure it by analyzing the PDF of intermittent events.Comment: Latex file, 8 pages + 5 postscript figure